期刊
CARBON
卷 96, 期 -, 页码 856-863出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2015.10.007
关键词
-
资金
- Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy [DE-AC0500OR22725]
- UT Battelle, LLC
- ARO [W911NF-10-1-0039]
- NSF [CET 1133112]
- Spanish Ministry of Economy and Competitively [CTQ2012-37925-C03-03]
- FEDER funds
CO2 interactions with nanoporous S- and N-doped polymer-derived carbon and commercial wood-based carbon were investigated in a broad range of conditions. The results showed that during CO2 adsorption nitrogen and sulfur species as well as water were released from the carbon surface as a result of chemical reactions of the surface groups with CO2. Inelastic neutron scattering experiments provided the unprecedented ability to characterize very small amounts of CO2 and H2O and revealed for the first time their physical/chemical status in the confined space of nanoporous carbons. The results obtained suggest that the reactivity of the carbon surface should be considered when CO2 storage media are chosen and when CO2 is used as a probe to determine the microporosity of carbon materials. (C) 2015 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据