期刊
ACS NANO
卷 14, 期 4, 页码 5111-5120出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.0c01976
关键词
MXene; silicon; structural stability; lithium-ion batteries; mechanical simulations
类别
资金
- National Natural Science Foundation [51972235]
- Natural Science Foundation of Shanghai [17ZR1447800]
- Program for Professor of Special Appointment (Eastern Scholar) at the Shanghai Institutions of Higher Learning
- Shuguang Program - Shanghai Education Development Foundation [18SG035]
- Shuguang Program - Shanghai Municipal Education Commission [18SG035]
- Hundred Youth Talent Plan of Tongji University
- Fundamental Research Funds for the Central Universities
Exploring Si-based anode materials with high electrical conductivity and electrode stability is crucial for high-performance lithium-ion batteries (LIBs). Herein, we propose the fabrication of a Si-based composite where Si porous nanospheres (Si p-NSs) are tightly wrapped by Ti3C2Tx (T-x stands for the surface groups such as -OH, -F) MXene nanosheets (TNSs) through an interfacial assembly strategy. The TNSs as a conductive and robust tight of the Si p-NSs can effectively improve electron transport and electrode stability, as revealed by substantial characterizations and mechanical simulations. Moreover, the TNSs with rich surface groups enable strong interfacial interactions with the Si p-NS component and a pseudocapacitive behavior, beneficial for fast and stable lithium storage. Consequently, the Si p-NS@TNSs electrode with a high Si content of 85.6% exhibits significantly enhanced battery performance compared with the Si p-NSs electrode such as high reversible capacity (1154 mAh g(-1) at 0.2 A g(-1)), long cycling stability (up to 2000 cycles with a 0.026% capacity decay rate per cycle), and excellent rate performances. Notably, the Si p-NS@TNSs electrode-based LIB full cell delivers a high energy uptake of 405 Wh kg(-1), many-times higher than that of the Si p-NSs full cell. This work offers a strategy to develop advanced Si-based anode materials with desirable properties for high-performance LIBs.
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