Growing Poly(norepinephrine) Layer over Individual Nanoparticles To Boost Hybrid Perovskite Photocatalysts

To address the poor stability of lead halide perovskite nanoparticles (NPs), monodisperse methylammonium lead bromide (MAPbBr(3), M-PE) NPs were successfully encapsulated with a thin layer (10 nm) of poly(norepinephrine) (PNE) by in situ polymerization. The PNE layer endowed M-PE NPs with high structural stability against severe environmental conditions. Furthermore, the chemical interaction between M-PE and PNE facilitates the construction of the core@shell composite, as well as contributes to the enhanced light-harvesting capacity and improved photoelectronic conversion efficiency in photocatalytic activity. The encapsulated NP M-PE@PNE with a band gap of 2.04 eV degraded the organic pollutant of malachite green by 81% in less than 2 h under visible light, which was 4.5 times higher than pristine M-PE NPs. This work provides a practical approach to stabilize and boost the MAPbX(3) photocatalyst and carries enormous potential in wide engineering applications.