期刊
CARBON
卷 105, 期 -, 页码 8-13出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2016.04.015
关键词
-
资金
- Samsung Research Fund, Sung-kyunkwan University
Electro-optical switching of graphene oxide (GO) liquid crystals is of great interest owing to its potential applications. However, a GO dispersion undergoes vinylogous carboxylic acidic reaction with time, accompanied by a decrease in pH, which deteriorates the electro-optical performance of a GO cell. We find that the vinylogous carboxylic reaction is hindered in high concentration GO dispersions, and also demonstrate that the deteriorating electro-optical performance can be recovered either by re-cleaning or by ionic neutralization treatment. The electro-optical performance is systematically analyzed in terms of the acidity of the neutralizing solvent, GO dispersion, and supernatant liquid. The best performance is obtained in a GO dispersion with a pH-7 supernatant liquid after neutralization by weakly alkaline water. The neutralization process decreases the bulk conductivity, and also improves the surface conductivity on GO. Approximately 56% of newly generated H+ ions reside near the GO surface, and the rest diffuse away into the bulk solvent. These findings may provide better understanding for the electro-optical switching phenomenon and its applicability. (C) 2016 Elsevier Ltd. All rights reserved.
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