期刊
CARBON
卷 100, 期 -, 页码 600-607出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2016.01.033
关键词
-
资金
- National Natural Science Foundation of China [51172068, 51372079, 51472082]
- Industry Support Program of Hunan Province [2014GK3102]
Graphene oxide in hard carbon/graphene composite is reduced by thermal treatment in inert atmosphere at a temperature in the range of 800-1100 degrees C. In this way, hard carbon/graphene composites with different effect of reduction on graphene oxide are obtained. Increasing heat treat temperature improves the reduction of graphene oxide (C/O atomic ratio in the range of 44-104) and diminishes the specific surface area and pore volume slightly. Furthermore, these materials behave as high-performance lithium ion battery electrodes and exhibit large reversible capacity (in the range of 300-480 mAh g(-1)) at current density of 20 mA g(-1), and superb stability over long-term cycling (78-82% of initial specific capacity after 500 cycles). Superior results are obtained with the electrode fabricated from the material treated at 1000 degrees C, which delivers 480 mAh g(-1) and 170 mAh g(-1) at current density of 20 and 2000 mA g(-1), respectively. In addition, interesting results are obtained that electrodes prepared by two types of copper foils display a significant difference on galvanostatic charge/discharge capacity. (C) 2016 Elsevier Ltd. All rights reserved.
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