期刊
CHEM
卷 6, 期 4, 页码 968-984出版社
CELL PRESS
DOI: 10.1016/j.chempr.2020.02.001
关键词
-
资金
- National Natural Science Foundation of China [21935003]
- National Key Research and Development Program of China [2016YFB0901500]
Rechargeable aqueous zinc-based batteries are very attractive alternative devices for current energy storage by virtue of their low cost and high security. However, the performance of vanadium oxide cathode strongly relies on the distance of interlayer spacing. Here, we employ layered PEDOT-NH4V3O8 (PEDOT-NVO) as a cathode material, which produces an enlarged interlayer spacing of 10.8 angstrom (against 7.8 angstrom for the single NVO) by effectively conducting polymer intercalation. This cathode material exhibits an improved capacity of 356.8 mAh g(-1) at 0.05 A g(-1) and 163.6 mAh g(-1), even at the highest current density of 10 A g(-1) (with a high retention from 0.05 to 10 A g(-1)), and features an ultra-long lifetime of over 5,000 charge-discharge cycles with a capacity retention of 94.1%. A combination of mechanism analyses and theoretical calculations suggest that the oxygen vacancies and larger interlayer spacing through polymer assistance account for the improved electrochemical performance.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据