期刊
CHEMISTRYSELECT
卷 5, 期 3, 页码 1146-1152出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201902444
关键词
Mechanical properties; PSA with diphenoxypyridine; Processability; Silicon-containing arylacetylene resin
资金
- Fundamental Research Funds for the Central Universities [50321041917001]
A novel silicon-containing arylacetylene resin called poly(dimethylsilylene-ethylene-phenoxypyridyloxy-phenylene-ethylene) (PSPPY) was made from 2,6-bis(4-ethynyl-phenoxy) pyridine and dimethyldichlorosilane by Grignard reactions. The structure and properties of the resin were characterized by H-1-NMR, FT-IR, GPC, XRD, DSC, TGA and universal testing machine. The resin has a wide processing window ranged from 35 degrees C to 155 degrees C. The cured resin shows excellent mechanical property, low dielectric property and high thermal stability. The flexural strength of the cured resin at room temperature reaches 58.7 MPa. The cured resin has dielectric constant 3.0-3.5, dielectric loss 0.008-0.040 in the frequency of 10(-1)-10(6) Hz, and low water uptake (0.8 %). The degradation temperature at 5 % weight loss and the residue at 800 degrees C of the cured resin arrive at 500 degrees C and 77.1 % in nitrogen atmosphere, respectively.
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