期刊
CHEMISTRYSELECT
卷 5, 期 5, 页码 1705-1708出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201903657
关键词
alpha-Acyloxy ketones; Carboxylic acid; Excellent selectivity; O-H insertion; Sulfoxonium ylide
资金
- Ningxia Key Research and Development Program [2018BEB04034, 2018BCG01001]
- Natural Science Foundation of Zhejiang Province P. R. China [LY18B020004]
A Ru-catalyzed method is developed for the synthesis of alpha-acyloxy ketones from sulfoxonium ylide and carboxylic acid. The strategy achieves an excellent selectivity in the presence of 1,10-phenanthroline as ligand to afford the corresponding product in good yields under simple conditions. The reaction is believed to provide an alternative method to generate ester compounds.
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