期刊
JOURNAL OF APPLIED CRYSTALLOGRAPHY
卷 53, 期 -, 页码 133-139出版社
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600576719016315
关键词
operando; batteries; pair distribution function analysis; depth profiling
资金
- NorthEast Center for Chemical Energy Storage, an Energy Frontier Research Center - US Department of Energy (DOE), Office of Science, Basic Energy Sciences [DE-SC0012583]
- US DOE Vehicle Technologies Office through the Advanced Battery Materials Research program (Battery500 Consortium) [DE-AC02-05CH11231]
- DOE Office of Science [DE-AC02-06CH11357, DE-SC0012704]
Operando studies that probe how electrochemical reactions propagate through a battery provide valuable feedback for optimizing the electrode architecture and for mitigating reaction heterogeneity. Transmission-geometry depth-profiling measurements carried out with the beam directed parallel to the battery layers - in a radial geometry - can provide quantitative structural insights that resolve depth-dependent reaction heterogeneity which are not accessible from conventional transmission measurements that traverse all battery layers. However, these spatially resolved measurements are susceptible to aberrations that do not affect conventional perpendicular-beam studies. Key practical considerations that can impact the interpretation of synchrotron depth-profiling studies, which are related to the signal-to-noise ratio, cell alignment and lateral heterogeneity, are described. Strategies to enable accurate quantification of state of charge during rapid depth-profiling studies are presented.
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