期刊
ENERGY TECHNOLOGY
卷 8, 期 5, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ente.202000010
关键词
lithium-ion batteries; potassium-ion batteries; Zn3V3O8 hollow spheres
资金
- Outstanding Young Scholar Project from South China Normal University [8S0256]
- National Natural Science Foundation of China [U1601214]
- National Natural Science Foundation of Guangdong Province [U1601214]
- Key Projects of Guangdong Province Nature Science Foundation [2017B030311013]
- Scientific and Technological Plan of Guangzhou City [201607010274, 201804010169]
- Department of Education of Guangdong Province [2018KTSCX047]
- Natural Science Foundation of Guangdong province [2019A1515011615]
Transition metal oxides have wide potential applications in high-performance energy-storage devices. Herein, hierarchically rambutan-like Zn3V3O8 (ZVO) hollow spheres are fabricated using a simple reflux/anneal strategy. These hollow spheres are enriched with highly porous features and a favorable surface area, which can afford abundant Li+/K+ transport paths, mitigate the volume dilatation, and boost the ion-storage capabilities. As the anodes for lithium-ion batteries, the ZVO electrodes can sustain a high discharge capacity of 1283.7 at 0.2 A g(-1) after 50 cycles. Even as the current density reaches 5 A g(-1), the reversible discharge capacity also remains 541 mA h g(-1) after 1000 long-term cycles. As the anodes for potassium-ion batteries, ZVO electrodes can afford a discharge specific capacity of 100.1 mA h g(-1) at 0.1 A g(-1) after 100 cycles. The results demonstrate that hierarchically rambutan-like ZVO hollow spheres can serve as a feasible candidate for Li+/K+ storage.
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