期刊
CHEMELECTROCHEM
卷 7, 期 5, 页码 1080-1083出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201902128
关键词
morphology effect; edge activity; oxygen evolution reaction; carbon cloth; CuCo2S4
资金
- National Natural Science Foundation of China [61774033]
- Key University Science Research Project of Anhui Province [KJ2017A712, KJ2017A713]
The different morphologies of CuCo2S4 have a significant effect on the electrocatalytic activity. However, the reasons for the activity difference of catalysts with multiple morphologies have raised little concern. Herein, we put forward the concept of active edge perimeter to evaluate the relative number of active sites. The morphologies are regulated by arranging NH4F from 0 to 3 mmol to prepare microsheet, tight-binding microsheet, hybrid microsheet/wire, long microwire and short wire morphologies. The long-perimeter microsheets can achieve a low Tafel slope (89 mV dec(-1)) and overpotential (283 mV) to reach a current density of 20 mA cm(-2) for the oxygen evolution reaction. For microsheets, the charge-transfer resistance is well under 50 % of the average values. The electrochemical surface area is above average area, owing to the high double-layer capacitance. Therefore, for two-dimensional microsheets, the long active perimeter is the main reason it ensures the high activity required for hierarchical catalysts.
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