期刊
CATALYSTS
卷 10, 期 2, 页码 -出版社
MDPI
DOI: 10.3390/catal10020216
关键词
hydrodechlorination; catalysts; organochlorine wastes; dichloroethane; kinetics; selectivity; conversion; technologies; tetrachloromethane; liquid/gas phase processes
The commercial implementation of hydrodechlorination processes will be an essential step in resolving the problem of environmentally sound organochlorine wastes processing. By now, there is a number of fundamental, applied, and process elaborations of such processes, in which chlorine is almost completely removed from wastes. The review article contains a significant number of results including basic regularities of thermal hydrodechlorination, comprehensive and selective catalytic hydrodechlorination. It discusses thermodynamics, kinetics, and catalysts of gas and liquid phase processes. Considerable attention is paid to hydrodechlorination of vinyl chloride production wastes and utilization of tetrachloromethane, which is the ozone-depleting substance. It also discusses hydrodechlorination of mono- and (poly)chlorobenzenes. The important examples of liquid phase data include hydrogenation using complex hydrides of elements. It also includes several flow sheets of hydrodechlorination processes.
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