期刊
CATALYSTS
卷 10, 期 2, 页码 -出版社
MDPI
DOI: 10.3390/catal10020146
关键词
TiO2; Cu; anti-corrosion; photoelectrochemical cathodic protection
资金
- Faculty of Engineering, Burapha University [WJP 13/2556]
- Research Unit of Developing Technology and Innovation of Alternative Energy for Industries
- Grant for International Research Integration: Chula Research Scholar, Ratchadaphiseksomphot Endowment Fund, Chulalongkorn University, Thailand
- Center of Excellence on Petrochemical and Materials Technology (PETROMAT), Thailand
- Petroleum and Petrochemical College, Chulalongkorn University, Thailand
Photochemical cathodic protection (PEC) efficiency was enhanced by doping TiO2 with Cu (Cu/TiO2) through impregnation and reduction under hydrogen. The Cu loading was vaired from 0.1 to 1.0 mol% (0.1 Cu/TiO2, 0.5 Cu/TiO2, 1 Cu/TiO2). Then, up to 50 wt% Cu/TiO2 was mixed with TiO2 to form nanocomposite films. The film photocurrent and photopotential were measured under 1 mW/cm(2) UV irradiation. The Cu/TiO2 film with 10 wt% of 0.5 Cu/TiO2 exhibited the highest photocurrent of 29.0 mA/g, which was three times higher than the TiO2 film. The underlying reason for the high photocurrent was the lower photopotential of film than the corrosion potential of copper for PEC. This film was also applied on copper terminal lug for anti-corrosion measurement by Tafel polarization in 3.5 wt% NaCl solution. The results showed that the photopotential of terminal lug coated with the film was -0.252 V vs. Ag/AgCl, which was lower than the corrosion potential of copper (-0.222 V vs. Ag/AgCl). Furthermore, the film can protect the corrosion of copper in the dark with 86.7% lower corrosion current (i(corr)) than that of bare copper.
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