期刊
NANO ENERGY
卷 68, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.nanoen.2019.104362
关键词
Perovskite solar cells; Bismuth-based solar cells; Bulk heterojunction; Energy band alignment; Exciton separation
类别
资金
- National Key Research and Development Program of China [2017YFA0206600, 2017YFA0402800]
- National Natural Science Foundation of China [61722403, 51572254, 51773045, 21572041, 21772030]
- Jilin Province Science and Technology Development Program [20190201016JC]
Bismuth-based lead-free perovskite solar cells are promising alternatives to the lead-based organic-inorganic hybrid cells which suffer from the environmental toxicity of lead and poor ambient stability, but the devices based on single-component ternary bismuth halides exhibit inferior power conversion efficiency. Herein, for the first time we construct bulk heterojunction (BHJ) bismuth-based perovskite solar cells with the photoactive layer consisting of in-situ phase-separated Cs3Bi2I9 and Ag3Bi2I9 components, achieving a record efficiency of approximate 3.6% and an unprecedented open-circuit voltage reaching 0.89 V. Formation of BHJ structure leads to increased crystal grain size of Cs3Bi2I9 and optimized grain orientation of Ag3Bi2I9, and a type-II energy band alignment is achieved, benefiting exciton separation and charge carrier transport. Cs3Bi2I9-Ag3Bi2I9 BHJ devices exhibit superb thermal stability, retaining similar to 90% of the initial efficiency after 450 h heating under 85 degrees C in glove box. Moreover, the universality of BHJ concept in boosting device performance of perovskite solar cells based on other reported AgxBiyIx+3y light-absorbers is verified. Our proof-of-concept breakthrough paves the way toward high-efficiency lead-free perovskite solar cells.
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