期刊
ADVANCED OPTICAL MATERIALS
卷 8, 期 8, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adom.201901919
关键词
double perovskites; ion doping; lead-free metals; nanocrystals; self-trapped excitons
资金
- National Natural Science Foundation of China [51571184, 21501165, 21875236, 21573211, 21633007]
- National Key R&D Program on Nano Science and Technology [2016YFA0200602, 2018YFA0208702]
- Fundamental Research Funds for the Central Universities [WK2060190085]
- Hefei National Synchrotron Radiation Laboratory [KY2060000111]
- Anhui Initiative in Quantum Information Technologies [AHY090200]
- Recruitment Program of Thousand Youth Talents
- USTC Center for Micro and Nanoscale Research and Fabrication
The exploration of lead-free halide perovskite nanocrystals (NCs) with intriguing optical properties is highly desirable owing to the toxicity and instability of lead halide perovskite NCs. Here, a new kind of uniform lead-free double perovskite Cs2NaBiCl6 NCs are reported as versatile hosts to accommodate ionic dopants for improving optical properties especially the photoluminescence (PL). In contrast to the low deep-blue PL with a quantum yield of only 1.7% of the as-synthesized pristine Cs2NaBiCl6 NCs, the PL of the Cs2NaBiCl6 NCs can be impressively regulated and enhanced via doping Ag+, Mn2+, or Eu3+ ions in the double perovskite lattices. The femtosecond time-resolved transient absorption spectroscopy is adopted to unravel the PL enhancement mechanism of the ion doping in the Cs2NaBiCl6 NCs. For the Ag+-doping, the excitonic absorption energy of the Cs2NaBiCl6 NCs can be tuned from 3.82 to 3.48 eV with the significant improvement of the PL quantum yield (PLQY) from 1.7% to 20%. The Mn2+-doped Cs2NaBiCl6 NCs show broad orange-red emission peak centered at 585 nm with a PLQY of 3%, owing to the T-4(1)->(6)A(1) transition of octahedrally coordinated Mn2+. Eu3+-doped Cs2NaBiCl6 NCs are endowed with strong Eu3+5D0 -> F-7(J) (J = 1, 2) orange-red emission at 591 and 615 nm.
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