Mesoporous Matrices as Hosts for Metal Halide Perovskite Nanocrystals

Several works have recently demonstrated that perovskite nanocrystals can be controllably formed within a variety of porous matrices employing diverse synthetic strategies. By means of the fine tuning of the pore size distribution, the thickness and composition of the walls, the geometry of the void network and its topology, strict control over the structural and morphological parameters of the hosted semiconductor can be achieved, determining its optical absorption and emission properties. Furthermore, porous hosts provide the guest semiconductor with enhanced stability and versatility in terms of processing, which favors its integration in devices. This article provides a comprehensive review of the different approaches proposed, as well as a discussion on the relevance they may have for the development of nanostructured perovskite-based optoelectronics. A critical assessment of the optical quality of the hybrid perovskite nanomaterials so obtained is presented, as well as an analysis of the fundamental and applied aspects of the nanocrystal-matrix interaction and a projected prospect of their impact in the fields of artificial lighting and renewable energy.