期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 8, 期 2, 页码 1178-1184出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.9b06321
关键词
sustainable chemistry; olefins; epoxidation; air; kinetic study; re-use; re-cycle
资金
- National Natural Science Foundation of China [21476041, U1608224, 61633006]
- State Key Laboratory of Fine Chemicals
A sustainable and practical protocol to prepare epoxides has been established by using air as the oxidant in the presence of K2CO3 in isopropylbenzene (CM) at 80-140 degrees C. The olefins are successfully converted into their corresponding epoxides in yields of up to 99%. CM and K2CO3 are reused in the scale-up recycling experiments. A reaction mechanism dominated by the radical pathway is proposed according to the control experiments and kinetic analysis.
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