期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 8, 期 7, 页码 2806-2813出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.9b06831
关键词
MoO2; N-doped carbon; ultralong cycling life; pseudocapacitive behavior; in situ XRD
资金
- Fundamental Research Funds for Central Universities of SCUT, China [2018ZD20]
- Guangzhou Science and Technology Program [20181002SF0115]
- National Science Foundation for Key Support Major Research project of China [91745203]
- Guangdong Innovative and Entrepreneurial Research Team Program [2014ZT05N200]
MoO2, a particular transition metal oxide that possesses high intrinsic electronic conductivity and a one-dimensional tunnel structure, is becoming a prospective material for fast energy storage. Herein, N-doped carbon-coated MoO2(MoO2@NC) nanoribbons are synthesized via the polymerization of pyrrole and its following pyrolysis using MoO3 nanoribbons as a precursor. When assembled as electrodes for Li+ storage, benefiting from the well-designed structure, the optimized MoO2@NC-1-1 electrode with suitable carbon coating exhibits not only high capacity but also good rate and cycling performance. Initial capacities of 1475 C g(-1) (similar to 410 mAh g(-1)) at 1 mV s(-1) and 100 C g(-1) at an extremely high sweep rate of 2000 mV s(-1) are achieved. The capacity is obviously enhanced along cycling, and 180% of the initial value is remained after 20,000 cycles of cycling. Through in situ XRD measurement, it is found that there is no phase change but high reversible expansion/shrinkage of several certain crystal planes of the MoO2 during the insertion and removal of Li+, which should contribute to the high durability of the MoO2@NC-1-1 electrode.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据