期刊
POLYMERS
卷 12, 期 1, 页码 -出版社
MDPI
DOI: 10.3390/polym12010198
关键词
thermotropic liquid crystalline copolymer; p-hydroxybenzoic acid; thermal property; C-13 solid-state nuclear magnetic resonance spectroscopy; molecular dynamics
资金
- Ministry of Trade, Industry & Energy (MOTIE, Korea) under the Industrial Technology Innovation Program [10063420]
- National Research Foundation of Korea (NRF) - Ministry of Education [2018R1D1A1B07041593]
- Korea Evaluation Institute of Industrial Technology (KEIT) [10063420] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2018R1D1A1B07041593] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Two series of thermotropic liquid crystal copolymers (TLCPs) with different monomer structures and compositions were synthesized. The copolymers in the first series consisted of 2,5-diethoxyterephthalic acid (ETA), hydroquinone (HQ), and p-hydroxybenzoic acid (HBA), whereas those in the second series contained ETA, 2,7-dihydroxynaphthalene (DHN), and HBA. In both series, the molar ratio of HBA to the other monomers varied from 0 to 5. The thermal properties, degree of crystallinity, and stability of the liquid crystalline mesophase of the copolymers obtained at each HBA ratio were evaluated and compared. Overall, at each HBA content, the DHN-containing copolymer had better thermal properties, but the HQ-containing copolymer exhibited a higher degree of crystallinity and a more stable liquid crystalline mesophase. Furthermore, similar thermal stabilities were observed in both series. The dependence of the molecular dynamics of the TLCPs on the monomer structure was explained using C-13 magic-angle spinning/cross-polarization nuclear magnetic resonance spectroscopy. An in-depth investigation of the relaxation time of each carbon revealed that the molecular motions of the TLCPs were greatly influenced by the structures of the monomers present in the main chain. The molecular dynamics of the HQ and DHN monomers in the two series were evaluated and compared.
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