期刊
ADVANCED ENERGY MATERIALS
卷 9, 期 48, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201902839
关键词
carbon coating; copper oxide; heterojunction; hydrogen evolution; photocatalysis
类别
资金
- National Natural Science Foundation of China [21671085, 21701063]
- Natural Science Foundation of Jiangsu Province [BK20161160, BK20191466]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Singapore Agency for Science, Technology and Research (A*STAR) AME IRG grant [A1783c0007]
CuO as a catalyst has shown promising application prospects in photocatalytic splitting of water into hydrogen (H-2). However, the instability of CuO in amine aqueous solution limits the applications of CuO-based photocatalysts in the photocatalytic H-2 evolution. In this work, a novel dodecahedral nitrogen (N)-doped carbon (C) coated CuO-In2O3 p-n heterojunction (DNCPH) is designed and synthesized by directly pyrolyzing benzimidazole-modified dodecahedral Cu/In-based metal-organic frameworks, showing long-term stability in triethanolamine (TEOA) aqueous solution and excellent photocatalytic H-2 production efficiency. The improved stability of DNCPH in TEOA solution is ascribed to the alleviation of electron deficiency in CuO by forming the p-n heterojunction and the protection with coated N-doped C layer. Based on detailed theoretical calculations and experimental studies, it is found that the improved separation efficiency of photogenerated electron/hole pairs and the mediated adsorption behavior (| increment G(H)(*)|-> 0) by coupling N-doped C layer with CuO-In2O3 p-n heterojunction lead to the excellent photocatalytic H-2 production efficiency of DNCPH. This work provides a feasible strategy for effectively applying CuO-based photocatalysts in photocatalytic H-2 production.
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