期刊
ACS CATALYSIS
卷 10, 期 5, 页码 3398-3403出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b05214
关键词
amide; C-C activation; C-H activation; arylation; rhodium catalysis; DFT
资金
- National Natural Science Foundation of China [21472128]
- Sichuan Science and Technology Program [2018JY560]
A rhodium-catalyzed transarylation of benzamides via selective C-C bond activation with arylboronic acids was described, which was distinct from the conventional metal-catalyzed C-N bond activation. This transformation exhibited good functional group compatibility with yields up to 88%, offering a practical approach for the construction and functionalization of benzamides. Preliminary experimental and computational studies revealed the selectivity of metal insertion into the C-C bond or the C-N bond was greatly affected by substituents on the amide's N atom.
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