Uncovering and quantifying the subduction zone sulfur cycle from the slab perspective

Sulfur belongs among H2O, CO2, and Cl as one of the key volatiles in Earth's chemical cycles. High oxygen fugacity, sulfur concentration, and delta S-34 values in volcanic arc rocks have been attributed to significant sulfate addition by slab fluids. However, sulfur speciation, flux, and isotope composition in slab-dehydrated fluids remain unclear. Here, we use high-pressure rocks and enclosed veins to provide direct constraints on subduction zone sulfur recycling for a typical oceanic lithosphere. Textural and thermodynamic evidence indicates the predominance of reduced sulfur species in slab fluids; those derived from metasediments, altered oceanic crust, and serpentinite have delta S-34 values of approximately -8, -1 parts per thousand, and+8 parts per thousand, respectively. Mass-balance calculations demonstrate that 6.4% (up to 20% maximum) of total subducted sulfur is released between 30-230km depth, and the predominant sulfur loss takes place at 70-100km with a net delta S-34 composition of -2.5 +/- 3 parts per thousand. We conclude that modest slab-to-wedge sulfur transport occurs, but that slab-derived fluids provide negligible sulfate to oxidize the sub-arc mantle and cannot deliver S-34-enriched sulfur to produce the positive delta S-34 signature in arc settings. Most sulfur has negative delta S-34 and is subducted into the deep mantle, which could cause a long-term increase in the delta S-34 of Earth surface reservoirs.