Sorption Studies of Chromate by Iron Oxide from Drinking Water

Chromium is well-thought-out heavy metal which is one of the enormously lethal due to its cancer-causing nature. In this study, iron oxide is used as adsorbent for chromate removal from aqueous solution as a function of pH, time, temperature, concentration of adsorbate and media dosage. The influence of pH on Cr (VI) sorption by iron oxide reveals that adsorption is significantly increased as pH is decreased from 8 to 2. The sorption rate is detected to be higher in the beginning and then it remains constant after 120 min of equilibrium time. The removal of Cr (VI) is found to be greater at higher temperature, which confirms the endothermic nature of Cr (VI) adsorption by iron oxide. Whereas, the kinetic investigations confirm that the chromate adsorption follows the pseudo second order with kinetic energy in the range of 8.4-83.7 kJ mol(-1).

Automated summary

The study found that the removal of hexavalent chromium by iron oxide is influenced by pH, time, temperature, and adsorbate concentration. The adsorption amount of chromium significantly increases as pH decreases, and the adsorption rate stabilizes after 120 minutes of equilibrium time. Higher temperature enhances the removal of hexavalent chromium, confirming the endothermic nature of the adsorption process.