期刊
THIN SOLID FILMS
卷 697, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2020.137794
关键词
Antiferroelectric films; sol-gel; pulsed laser deposition; energy storage; thermal stability
类别
资金
- National Foundation for Science and Technology Development (NAFOSTED) of Vietnam [103.99-2018.23]
Antiferroelectric PbZrO3 (PZO) thin-films were fabricated by pulsed laser deposition (PLD) and sol-gel techniques to investigate the effect of antiferroelectric-ferroelectric (AFE-FE) phase transition on the energy storage performance. The (100)-oriented PLD thin-films have a square-double polarization-electric field (P-E) hysteresis loop with a sharp-phase transition and the (111)-oriented sol-gel thin-films have a slanted P-E loop with a diffused-phase transition. The difference in the phase transition fields between PLD and sol-gel thin-films could be attributed to their difference in crystalline orientations. In this case, the antipolar AFE phase is along the [110]-direction of the original tetragonal-cell under zero electric-field, while the antipolar AFE phase switches into the polar FE phase under a strong enough electric-field and the tetragonal-cell becomes rhombohedral with the polar direction of [111]. Due to the larger maximum polarization and slimmer P-E loop, the higher recoverable energy-storage (U-reco) of 19.4 J/cm(3) and larger energy-efficiency (eta) of 70.8%, are achieved in sol-gel thin-films. More importantly, this film shows excellent charge-discharge cycling endurance of both U-reco and eta values after 10(10) cycles and good thermal-stability under a wide operating temperature. From the viewpoint of applications, the sol-gel method is considered to be a promising approach towards producing low-cost PZO thinfilms for high-efficiency energy-storage devices over a broad temperature range.
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