期刊
TALANTA
卷 207, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.talanta.2019.120314
关键词
Simultaneous speciation; Selenium; Tellurium; Polyaniline; Magnetic solid phase extraction; Inductively coupled plasma mass spectrometry
资金
- National Natural Science Foundation of China [21575107, 21675118, 21775113]
- Science Fund for Creative Research Groups of NSFC [20921062]
- Large-Scale Instrument and Equipment Sharing Foundation of Wuhan University [LF20191236]
Herein, polyaniline functionalized magnetic nanoparticles (MNPs) were prepared and investigated as the adsorbents for the separation and enrichment of inorganic selenium and tellurium species. The prepared Fe3O4@SiO2@polyaniline (PANI) MNPs presents selective adsorption performance for Se-IV and Te-IV, along with fast adsorption and desorption dynamics. Based on it, a method combining magnetic solid phase extraction (MSPE) with inductively coupled plasma mass spectrometry (ICP-MS) was developed for the simultaneous speciation of inorganic Se and Te in environmental waters. The adsorption mechanism was investigated preliminarily. Various parameters affecting Fe3O4@SiO2@PANI MSPE of Se-IV and Te-IV were investigated. Under the optimized conditions, the limits of detection (3 sigma) for Se-IV and Te-IV were found to be 5.3 and 1.2 pg mL(-1) with the relative standard deviations (c(se(IV))) = 100 pg mL(-1), c(Te(IV))) = 10 pg mL(-1), n = 7) of 3.8 and 8.0%, respectively. The enrichment factor of the proposed method is 100-fold. The proposed method was successfully applied to the speciation of inorganic Se and Te in environmental water samples. The developed MSPE-ICP-MS method possesses the advantages of low cost, high enrichment factor, rapid operation and can simultaneously analyze inorganic Se and Te species in real-world samples.
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