期刊
SYNLETT
卷 31, 期 5, 页码 463-468出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1690796
关键词
photooxygenation; singlet oxygen; substrate selectivity; BODIPY; oxidation
资金
- Conseil Regional des Pays de la Loire (NANO2 project)
- University of Nantes
- CNRS
Substrate selectivity by means of synthetic catalysts remains a challenging topic in chemistry. Here, a catalytic system combining an iodo-BODIPY photosensitizer and quinine was evaluated in the competitive photooxygenation of non-hydrogen and hydrogen-bond-donor substrates. The ability of quinine to activate hydrogen-bond-donor substrates towards photooxygenation was reported and the results were benchmarked with photooxygenation experiments in the absence of quinine.
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