期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 307, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2020.127655
关键词
SO2 sensor; ppb-level; SrMoO4; Stabilized zirconia; Mixed-potential
资金
- National Nature Science Foundation of China [61831011, 61803171, 61520106003, 61722305, 61833006]
- Program for Chang Jiang Scholars and Innovative Research Team in University [IRT-17R47]
- National Key Research and Development Program of China [2016YFC0207300, 2016YFC0201002]
- Application and Basic Research of Jilin Province [20130102010 JC]
- Young Elite Scientists Sponsorship Program by CAST [2018QN RC001]
- Program for JLU Science and Technology Innovative Research Team [JLUSTIRT 2017TD-07]
- China Postdoctoral Science Foundation [2018M630322, 2019T120239]
- Jilin Provincial Science and Technology Development Program [20190103155JH]
- Jilin Provincial Education Department Science and Technology Project [JJKH20190114KJ]
- Fundamental Research Funds for the Central Universities
The planar yttria-stabilized zirconia (YSZ) solid electrolyte based mixed potential type gas sensing devices attached with molybdate MMoO4 (M: Ni, Co, Zn, Mn and Sr) sensing electrodes (SEs) were designed and fabricated, attempting to sensitively and rapidly monitor ppb-level SO2. The sensor using SrMoO4-SE possessed the highest potential response signal of -37.5 mV to 500 ppb SO2 at 550 degrees C. More importantly, the low detection limit of 20 ppb SO2 and fast response time of 37 s to 200 ppb SO2 were presented for the device utilizing SrMoO4-SE at 550 degrees C. The linear dependence between response value and the SO2 concentration logarithm in the range of 0.02-1 ppm was observed, which the sensitivity (slop) was -29 mV/decade. Furthermore, the sensor also showed excellent selectivity, reproducibility and high temperature stability of 7 days to SO2 at 550 degrees C. The mixed potential sensing mechanism was discussed and further verified based on the measurement of polarization curves.
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