期刊
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B
卷 13, 期 6, 页码 975-985出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1990793119060113
关键词
adsorption isotherm; equilibrium simulation; multilayer binding
资金
- Program for Basic Research of the Institute of Chemical Physics, Russian Academy of Sciences [46.15, 0082-2014-0005, AAAA-A17-117091220076-4]
The possibilities of calculating adsorption equilibria by simulating a set of kinetic stages of sorption and desorption are considered. An approach is proposed in which an adsorption isotherm is obtained by scanning the concentration of the adsorbed substance in a simulation program as a linear function of time. The principal possibility of obtaining the adsorption isotherms of five types out of the six approved by IUPAC (except for the multistage one of type VI) is shown. To obtain undistorted adsorption isotherms, it is necessary and sufficient to use a scanning step larger than the time constant for establishing the adsorption equilibrium. It is shown that the polymolecular Brunauer-Emmett-Teller adsorption isotherm can be simulated with high accuracy using a simple kinetic scheme.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据