期刊
PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL
卷 30, 期 2, 页码 160-167出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.pnsc.2020.01.021
关键词
Spinel photocatalyst; Visible light; Photodegradation; Atrazine; Magnetic separation
资金
- Research Center for Advanced Materials (RCAMS) at King Khalid University [RCAMS/KKU/006-19]
Atrazine (ATZ) is a known herbicide used in agriculture and caused many concerns according to its toxicity. Herein, we have prepared NiCo2O4 nanorods that can work as a photocatalyst under visible light exposure by Ag loading through a simple route. The characterizations revealed the role of Ag for improving the structural, optical and optoelectronic properties of the produced photocatalyst. The Ag loading with 5 wt% confirms the minimization of the bandgap from 3.6 down to 2.57 eV with enhanced visible light absorption and sustaining the magnetic properties. The Ag/NiCo2O4 nanorods showed a superior photodegradation of ATZ within 20 min at 2.0 g L-1 with excellent recyclability. The enhancement of the photocatalytic activity is referred to the local surface plasmon resonance of Ag-loaded photocatalyst. This reduces the electron-hole recombination and out-performs the unloaded sample. This work is highlighting the application of magnetically separable spinel photocatalysts for the removal of herbicides and water remediation.
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