期刊
BIOSENSORS & BIOELECTRONICS
卷 63, 期 -, 页码 513-518出版社
ELSEVIER ADVANCED TECHNOLOGY
DOI: 10.1016/j.bios.2014.08.005
关键词
Periodate; Fluorescent probe; Ratiometric detection; Excited-state intramolecular proton transfer
类别
资金
- National Natural Science Foundation of China [21302125, 21373138]
- Doctoral Fund of Ministry of Education of China [20133127120005]
- Program for Shanghai Sci. & Tech. Committee [13ZR1458800, 12JC1407200]
- Program for Cultivation of Young Teacher of Shanghai University
- The Innovative Program of Shanghai Normal University [SK201331]
- Science and Technology Innovation Foundation for College Students [2012+10270+115]
Periodate is widely used in organic and bioorganic chemistry, and also related to food and environmental safety. To best of our knowledge, there is no efficient tools reported for simultaneously quantifying periodate with high accuracy and discriminating periodate from other forms of iodine. We have synthesized, characterized and applied a first ratiometric fluorescent probe (PDS-2) for simultaneous monitoring of changes of periodate based on the excited-state intramolecular proton transfer mechanism. This PDS-2 based fluorescent technique may enable for a better understanding of periodate related biological and chemical processes. Also, it is an efficient tool for public health, food safety and environmental protection. (C) 2014 Elsevier B.V. All rights reserved.
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