期刊
ORGANIC LETTERS
卷 22, 期 5, 页码 2026-2031出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00405
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资金
- National Natural Science Foundation of China [21472094, 21772096]
- National Key R&D Program of China [2017YFD020030202]
- Tianjin Natural Science Foundation [17JCYBJC20300]
Herein we report the design and synthesis of hypervalent trifluoromethylthio-iodine(III) reagent 1 and the elucidation of its structure by NMR spectroscopy and X-ray crystallography. The trifluoromethylthiolation reactions of 1 with various nucleophiles were explored, and this compound was found to be a versatile electrophilic reagent for the transfer of a trifluoromethylthio group (-SCF3). The hydrogen-bonding mode responsible for the activation of 1 by the solvent 1,1,1,3,3,3-hexafluoro-2-propanol was investigated both experimentally and computationally.
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