期刊
ORGANIC LETTERS
卷 22, 期 5, 页码 1934-1940出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00295
关键词
-
资金
- Scientific Research Foundation of China [21772018, 21922101, 21901026]
An organocatalyzed enantioselective gamma-elimination process has been achieved and applied in the kinetic resolution of peroxides to access chiral peroxides and epoxides. The reaction provided a pathway for the preparation of two useful synthetic and biologically important structural motifs through a single-step reaction. A range of substrates has been resolved with a selectivity factor up to 63. The obtained enantioenriched peroxides and epoxides allowed a series of transformations with retained optical purities.
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