期刊
ORGANIC LETTERS
卷 22, 期 4, 页码 1485-1489出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00063
关键词
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资金
- National Natural Science Foundation of China [21971068, 21772044]
- National Young Top-Notch Talent Support Program
- Program of Shanghai Academic/Technology Research Leader [18XD1401500]
- Program of Shanghai Science and Technology Committee [18JC1411303]
- Program for Changjiang Scholars and Innovative Research Team in University
- Fundamental Research Funds for the Central Universities
A new approach was developed to construct the tetrahydroxanthone by a Knoevenagel condensation/6 pi-electronic cyclization/aromatization cascade starting from readily available cyclohexane-1,3-diones and unsaturated aldehydes. This strategy provides a new solution for the preparation of monomeric tetrahydroxanthones bearing different functional groups at C-12. As a synthetic application, the asymmetric formal synthesis of rugulotrosin A was achieved.
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