期刊
ORGANIC LETTERS
卷 22, 期 4, 页码 1655-1658出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00247
关键词
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资金
- College of Chemistry and Molecular Engineering, Peking University
- PekingTsinghua Center for Life Sciences, Beijing National Laboratory for Molecular Sciences
- National Science Foundation of China [31521004, 21672011, 21822101, 21977002]
- National Key Research and Development Program of China [2017YFA0104003]
- PKUAIC
- High -Performance Computing Platform of Peking University
A novel strategy to construct the highly oxidized 3-oxabicyclo[3.3.0]octane skeleton was developed via a gold-catalyzed cascade cyclization with 2,7-dioxabicyclo[3.2.0]hept-3-ene as the substrate. We utilized this methodology as the key reaction to synthesize 17-deacetoxyl chromodorolide B.
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