期刊
ORGANIC LETTERS
卷 22, 期 4, 页码 1265-1269出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b04508
关键词
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资金
- National Natural Science Foundation of China [21702056, 21971059, 21702055]
- National Program for Thousand Young Talents of China
- Fundamental Research Funds for the Central Universities
We develop herein an efficient rhodium-catalyzed remote isomerization of aromatic and aliphatic alkenyl alcohols into ketones. This catalytic process, with a commercially available catalyst and ligand ([RhCl(cod)](2) and Xantphos), features high efficiency, low catalyst loading, good functional group tolerance, a broad substrate scope, and no (sub)stoichiometric additive. Preliminary mechanistic studies suggest that this transformation involves an iterative dissociative beta-hydride elimination-migration insertion process.
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