期刊
ORGANIC LETTERS
卷 22, 期 4, 页码 1331-1335出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b04590
关键词
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资金
- National Science Foundation for Distinguished Young Scholars of China [21525101]
- NSF of Hubei
- Guangxi Province [2018CFB156, 2017CFA006, 2017GXNSFDA198040]
- Program of Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules [KLSAOFM1702]
- Foreign Experts Recruitment Program of Guangxi province [GX2019014]
- BAGUI talent program [201904]
- CNRS-France
Ru(II)-catalyzed direct alkylation of tertiary phosphines via hydroarylation of activated olefins promoted by mono-N-protected amino acid (MPAA) was achieved. This protocol provides a straightforward access to a large library of Buchwald-type bulky alkylated monophosphines from commercially available biaryl phosphine. Moreover, two ruthenacycle intermediates of tertiary phosphines via C-H bond cleavage were isolated to illustrate the mechanism of P(III)-directed C-H activation.
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