期刊
ORGANIC LETTERS
卷 22, 期 4, 页码 1385-1389出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00002
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资金
- Natural Science Foundation of Shanghai [19ZR1468700]
- CAS Key Laboratory of Synthetic Chemistry of Natural Substances
- Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
A mild and efficient protocol for the intramolecular aromatic C-H oxygenation of 2-biphenylcarboxylic acids has been achieved via iron photocatalysis. The 2-biphenylcarboxylic acids with a diverse array of substituents at both phenyl rings could furnish the oxygenation products in good to excellent yields. We speculate that the aryl carboxylate-iron(III) complexes should generate the aroyloxy radicals and iron(II) upon visible light irradiation.
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