期刊
ORGANIC LETTERS
卷 22, 期 4, 页码 1490-1494出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00071
关键词
-
资金
- NSFC [21772218, 21821002]
- State Key Laboratory of Organometallic Chemistry
- Shanghai Institute of Organic Chemistry
- Chinese Academy of Sciences
- [XDB20000000]
A photoinduced, copper-catalyzed, highly enantioselective dual alkylation/arylation and alkynylation of alkene is reported. A single chiral copper(1) complex serves to enable photoredox catalysis and induce enantioselectivity during the reaction. This reaction couples three different components under mild reaction conditions, exhibits a broad substrate scope, and provides facile access to chiral propargylic systems, including those featuring valuable fluorinated substituents.
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