期刊
ORGANIC LETTERS
卷 22, 期 6, 页码 2235-2239出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00433
关键词
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资金
- Institute of Global Prominent Research, Chiba University
- JSPS KAKENHI [G18K14863]
In this study, a visible-light-induced intermolecular C-H bond imidation of arenes was achieved at ambient condition. By using simple phthalimide with (diacetoxyiodo)benzene and molecular iodine, direct metal-/photocatalyst-free C-N bond formation was achieved. The imidation protocol was designed by using time-dependent density functional theory calculations and experimentally demonstrated for 28 substrates with as high as 96% yield. Mechanistic studies indicated that radical-mediated aromatic substitution occurred via photolysis of N-iodophthalimide under visible-light irradiation
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