期刊
ORGANIC LETTERS
卷 22, 期 6, 页码 2419-2424出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00622
关键词
-
资金
- Natural Science Foundation of China [21572118, 21971149]
- Tang Scholar Award
- Fundamental Research Funds of Shandong Univ.
A kinetically controlled radical addition/elimination reaction generating fluorinated allenes was developed. This strategy offers a route to a facile synthesis of diverse trifluoromethyl, difluoromethylene, and perfluoroalkyl functionalized allenes from readily available fluoroalkyl halides and alkynyl aziridines under visible-light irradiation. Density functional theory calculation of this radical clock type of reaction revealed a kinetically controlled C-N bond cleavage overcoming the alternative thermodynamically controlled C-C bond cleavage process.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据