期刊
ORGANIC LETTERS
卷 22, 期 3, 页码 965-969出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b04503
关键词
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资金
- National Natural Science Foundation of China [21602001, 21922109, 21672196, 21831007]
- Nanjing Tech University [39837134]
- Fundamental Research Funds for the Central Universities of China [WK2060190086]
A regioselective Wacker-Tsuji oxidation of internal olefins in (BuOH)-Bu-t has been developed using oxygen as the terminal oxidant and tert-butyl nitrite as the simple organic redox cocatalyst without the involvement of hazardous cocatalysts or harsh reaction conditions. A series of internal olefins bearing various functional groups can be oxidized to the corresponding substituted ketones in generally good yields with high regioselectivities.
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