期刊
ORGANIC LETTERS
卷 22, 期 3, 页码 934-938出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b04486
关键词
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资金
- National Natural Science Foundation of China [81773602]
- Natural Science Foundation of Guangdong Province [2019A1515011694]
- Pearl River Science and Technology New Star Fund of Guangzhou [201605120849569]
- Guangdong Special Support Program [2017TQ04R599]
The first concise total syntheses of sanctis A and B were reported, and it enabled revision of the structure of sanctis B through single-crystal X-ray diffraction. The established synthetic approach mainly mimics a biosynthetic olefin isomerization/hemiacetalization/dehydration/[3 + 3]-type cycloaddition cascade sequence, offering a viable synthetic methodology to efficiently access sanctis A-B and their analogues.
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