期刊
ORGANIC LETTERS
卷 21, 期 24, 页码 9924-9928出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03862
关键词
-
资金
- Key Projects of the Preresearch Fund of the General Armament Department [6140720020101, 61407200204]
- National Natural Science Foundation of China [51572230]
- National Defense Technology Foundation Project [JSJL2016404B002]
- Institute of Chemical Materials, China Academy of Engineering Physics
The regioselective synthesis of fullerene bis-adducts remains challenging because it produces large amounts of regioisomers. Novel nontethered cis-1 and cis-2 bis(benzofuro)[60]fullerene derivatives were directly synthesized with high regioselectivity by using chlorofullerene C60C16 as a precursor. Their structures were determined via spectroscopic data and single-crystal X-ray analysis. A nucleophilic addition elimination mechanism was proposed to elucidate the formation of highly regioselective cis-1 and cis-2 bis-adducts. The potential application of these bis(benzofuro)[60]fullerene derivatives as stabilizers in propellants was also investigated.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据