期刊
NANO RESEARCH
卷 13, 期 1, 页码 225-230出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-019-2604-4
关键词
molybdenum disulfide; interlayer expansion; potassium ion batteries; hierarchical structure
类别
资金
- National Natural Science Foundation of China [51972219]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Collaborative Innovation Center of Suzhou Nano Science and Technology
Potassium-ion batteries are regarded as the low-cost alternative to lithium-ion batteries. However, their development is hampered by the lack of suitable electrode materials. In this work, we demonstrate that MoS2 with expanded interlayers represents a promising candidate for the electrochemical storage of potassium ions. Hierarchical interlayer-expanded MoS2 assemblies supported on carbon nanotubes are prepared via a straightforward solution method. The increased interlayer spacing not only enables the better accommodation of foreign ions, but also lowers the diffusion energy barrier and improves diffusion kinetics of ions. When investigated as the anode material of potassium ion batteries, our interlayer-expanded MoS2 assemblies exhibit an excellent electrochemical performance with large capacity (up to similar to 520 mAhg(-1)), good rate capability (similar to 310 mAhg(-1) at 1,000 mAg(-1)) and impressive cycling stability, superior to most competitors.
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