期刊
NANO LETTERS
卷 20, 期 2, 页码 1240-1251出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.nanolett.9b04661
关键词
2D perovskite; alkali cation doping; improved 2D perovskite structural stability; hysteresis; long-term device stability
类别
资金
- Australian Research Council (ARC) [DP160104575]
- Australian Centre for Advanced Photovoltaics (ACAP)
- Australian Renewable Energy Agency
- ARC Centre of Excellence in Exciton Science [ACEx:CE170100026]
- National Key RAMP
- D Program of China [2017YFE0106000]
- National Natural Science Foundation of China [51773212, 21574144, 61705240, 21674123]
- Zhejiang Provincial Natural Science Foundation of China [LR16B040002]
- Ningbo SAMP
- T Innovation 2025 Major Special Programme [2018B10055]
- Ningbo Municipal Science and Technology Innovative Research Team [2015B11002, 2016B10005]
- CAS Key Project of Frontier Science Research [QYZDB-SSW-SYS030]
- CAS Key Project of International Cooperation [174433KYSB20160065]
3D/2D hybrid perovskite systems have been intensively investigated to improve the stability of perovskite solar cells (PSCs), whereas undesired crystallization of 2D perovskite during the film formation process could undermine the structural stability of 2D perovskite materials, which causes serious hysteresis of PSCs after aging. This issue is, however, rarely studied. The stability study for 3D/2D hybrid systems to date is all under the one-direction scan, and the lack of detailed information on the hysteresis after aging compromises the credibility of the stability results. In this work, by correlating the hysteresis of the hybrid PSCs with the 2D crystal structure, we find that the prompt 2D perovskite formation process easily induces numerous crystal imperfections and structural defects. These defects are susceptible to humidity attack and decompose the 2D perovskite to insulating long-chain cations and 3D perovskite, which hinder charge transfer or generate charge accumulation. Therefore, a large hysteresis is exhibited after aging the 3D/2D hybrid PSCs in an ambient environment, even though the reverse-scan power conversion efficiency (PCE) is found to be well-preserved. To address this issue, alkali cations, K+ and Rb+, are introduced into the 2D perovskite to exquisitely modulate the crystal formation, which gives rise to a higher crystallinity of 2D perovskite and a better film morphology with fewer defects. We achieved PCE beyond 21% due to the preferable charge transfer process and reduced nonradiative recombination losses. The structural features also bring about impressive moisture stability, which results in the corresponding PSCs retaining 93% of its initial PCE and negligible hysteresis after aging in an ambient atmosphere for 1200 h.
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