期刊
MONATSHEFTE FUR CHEMIE
卷 151, 期 1, 页码 99-106出版社
SPRINGER WIEN
DOI: 10.1007/s00706-019-02535-y
关键词
Copper; Cross-coupling; C-N cleavage; Arylmethyl quaternary ammonium salts; Dialkylphosphine oxides
资金
- State Key Laboratory of Geohazard Prevention and Geoenvironment Protection [SKLGP2018Z002]
A ligand-free copper-catalyzed C-P cross-coupling reaction of arylmethyl quaternary ammonium salts and diarylphosphine oxides in air is developed. Arylmethyl quaternary ammonium salts with various functional groups and a variety of dialkyl- and diarylphosphine oxides afford C-P cross-coupling products with good yields. This protocol requires no inert atmosphere, no ligand, and simple operation steps.
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