期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 295, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.micromeso.2019.109972
关键词
Nano catalyst; Buchwald-Hartwig coupling; Mesoporous; Copper; Polymeric carbon nitride
类别
资金
- National Key Research and Development Program of China [2018YFD0200100]
- Blue Green Project at Yangzhou Polytechnic Institute
- Jiangsu College Students' Innovation and Entrepreneurship Training Program [201813754010Y]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
By calcining melamine with Cu(NO3)(2)center dot 3H(2)O, Cu-anchored polymeric carbon nitride (Cu/PCN) was prepared. SEM and TEM images demonstrated this material was constituted by PCN nanotubes with ca 50 nm diameters involving a variety of ca 5-10 nm-sized mesoporous substructures. The unique porous structures allowed sufficient contact of the reactants with the catalytic Cu sites, resulting in superior catalytic activities of the material over traditional catalysts in Buchwald-Hartwig coupling of pyrimidines, which was a significant transformation in pharmaceutical industry.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据