期刊
MAGNETIC RESONANCE IN CHEMISTRY
卷 58, 期 7, 页码 641-647出版社
WILEY
DOI: 10.1002/mrc.4997
关键词
benchtop NMR; dendrimer; DOSY; hydrodynamic radius
资金
- College of the Ozarks
Benchtop nuclear magnetic resonance (NMR) spectroscopy is a useful tool for the rapid determination of the self-diffusion coefficient and the hydrodynamic radius of dendrons. The self-diffusion coefficients of the first four generations of poly ethoxy ethyl glycinamide (PEE-G) dendrons are measured by diffusion-ordered spectroscopy (DOSY) on a benchtop NMR equipped with diffusion gradient coils. The hydrodynamic radii of the dendrons are calculated via the Stokes-Einstein equation. The effects of solvent and pH are determined with the hydrodynamic radius increasing with generation and decreasing upon neutralization of an acidic solution. These measurements provide valuable information for biological and pharmaceutical applications of dendrons.
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