期刊
MACROMOLECULES
卷 53, 期 1, 页码 51-58出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.9b02266
关键词
-
资金
- National Research Foundation (NRF) Investigatorship in Singapore [NRF-NRFI05-2019-0001]
- Academic Research Fund (AcRF) Tier 2 from Ministry of Education in Singapore [MOE2017-T2-1-018]
Quaternary ammonium iodide (R4N+I-) catalysts immobilized on silica particles, Fe3O4 magnetic particles, and organic resin particles were developed for organocatalyzed living radical polymerization. A random copolymer containing the catalytic R4N+I- moieties and the anchoring triethoxysilyl moieties was synthesized and immobilized onto silica and Fe3O4 particles to give the silica particle- and Fe3O4 particle-supported R4N+I- catalysts. A tertiary-amine-containing polymer resin particle was quaternized to give the resin particle-supported R4N+I- catalyst. The supported catalysts were successfully used to synthesize homopolymers and block copolymers of methyl methacrylate, functional methacrylates, styrene, and acrylonitrile with low dispersities. The supported catalysts were able to be separated (recovered) from the polymerization solutions in simple manners, that is, with centrifugation or with a magnet. The catalysts were reused in five polymerization cycles without a noticeable decrease in the catalytic efficiency. The facile preparation of the supported catalysts, the broad monomer scope, and the feasibility of the catalyst reuse and recycle are attractive features.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据