期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 221, 期 5, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201900493
关键词
bromined phenyl-carbamate bond; high refractive indices; polyurethane; recyclability; tertiary amine catalysts
资金
- National Natural Science Foundation of China [51473114]
The applications of polyurethane (PU) thermosets are limited by the lack of plasticity after curing due to permanent crosslinks. Besides, the low refractive index is insufficient for optical devices. Here, a transparent, high refractive, recyclable, and healable PU thermoset is developed based on dynamic bromined phenyl-carbamate bonds (BPCB). It exhibits tensile strength of approximate to 52 MPa, good shape-memory ability, and can be reprocessed or healed nearly completely at 110 degrees C in 30 min. Tertiary amine catalysts and bromine substituents jointly play unexpected roles to promote the forward and reverse reactions significantly, leading to high bond-exchange efficiency of BPCB. Furthermore, the introducing of BPCB can endow the material with higher refractive index (n(D) = 1.5850) simultaneously. In summary, this material is of potential as dynamic PU thermoset in various fields, especially in advanced optical devices.
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